Rosa Arrigo

Rosa Arrigo (WoS Researcher ID L-6676-2016) is lecturer in Inorganic Chemistry at the University of Salford in Manchester (UK) and honorary research scientist at the UK’ s synchrotron facility Diamond Light Source. Her research interests are focused on the design of innovative processes and nanostructured systems for decarbonization technologies in green chemistry and energy storage and conversion. Her research strategy consists of establishing molecular level structure-function relationships through the controlled synthesis of tailored materials, testing and thorough structural characterisation, including but not limited to the extensive use of innovative in situ synchrotron-based techniques such as X-ray photoelectron spectroscopy and X-ray absorption fine structure spectroscopy. Current projects focus the conversion of carbon dioxide and H2 production. Recently, she is investigating the host/guest chemistry in metal-organic frameworks for the delivery of Aspergillus derived drugs.

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Selected Publications of Relevance to Catalysis Science (last three years).

·       Dynamics at Polarized Carbon Dioxide–Iron Oxyhydroxide Interfaces Unveil the Origin of Multicarbon Product Formation, R. Arrigo, R. Blume, V. Streibel, C. Genovese, A. Roldan, M. E. Schuster, C. Ampelli, S. Perathoner, J. J. Velasco Vélez, M. Hävecker, A. Knop-Gericke, R. Schlögl, G. Centi, ACS Catal. 2022, 12, 1, 411–430.

● Elucidating the mechanism of the CO2 methanation reaction over Ni/hydrotalcite-derived catalysts via surface sensitive in situ XPS and NEXAFS, G. Giorgianni, C. Mebrahtu, M. E. Schuster, A. I. Large, G. Held, P. Ferrer, F. Venturini, D. Grinter, R. Palkovits, S. Perathoner, G. Centi, S. Abate, *R. Arrigo, Phys. Chem. Chem. Phys. 2020, DOI: 10.1039/D0CP00622J.         

•   Operando X-ray absorption fine structure study of the electrocatalytic reduction of carbon dioxide over Ferrihydrite on nitrogen-doped carbon, C. Genovese, M. E. Schuster, E. K. Gibson, D. Gianolio, V. Posligua, R. Grau-Crespo, G. Cibin, P. P. Wells, D. Garai, V. Solokha, S. Krick Calderon, J. Velasco Velez, C. Ampelli, S. Perathoner, G. Held, G. Centi, *R. Arrigo, Nat. Comms. 9, 2018, 935. doi:10.1038/s41467-018-03138-7.

•   In situ observation of reactive oxygen species forming on oxygen-evolving iridium surfaces, V. Pfeifer, *T. E. Jones, J. J. Velasco Vélez, *R. Arrigo, S. Piccinin, M. Hävecker, A. Knop-Gericke, R. Schlögl, Chem. Sci. 8, 2017, 2143-2149. DOI: 10.1039/C6SC04622C.

Recent Press Releases

“Take a Tour of the Diamond Light Source” in Chemistry world,

“Carbon Dioxide Conversion to Hydrocarbon: Thinking Big to See Small Things”,

 “Understanding Catalysts and Catalysis”,